Citation: Rafieh-Sadat Norouzian, Moslem M. Lakouraj, Ehsan N. Zare. Novel Conductive PANI/Hydrophilic Thiacalix[4]arene Nanocomposites：Synthesis, Characterization and Investigation of Properties[J]. Chinese Journal of Polymer Science, ;2014, 32(2): 218-229. doi: 10.1007/s10118-014-1402-4 shu

Novel Conductive PANI/Hydrophilic Thiacalix[4]arene Nanocomposites：Synthesis, Characterization and Investigation of Properties

1.
Polymer Chemistry Research Laboratory, Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar 47416-95447, Iran

Corresponding author: Moslem M. Lakouraj,
Received Date: 13 May 2013
Revised Date: 30 June 2013

Nanocomposites of polyaniline (PANI) and the macrocycle thiacalix[4]arene tetra sulfonate (TCAS) were successfully synthesized in feed ratios of 1:0.25, 1:0.50 and 1:0.75 by three prevail synthetic methods, i.e. in situ polymerization, emulsion polymerization and solution casting technique. The structures of the nanocomposites were confirmed by FTIR, UV-Vis, XRD, SEM, and TEM techniques. The conductivity was measured by a four probe method. The conductivity was recorded to be as high as 10510-2 Scm-1 for the nanocomposite with a nanometer size structure and homogeneously distributed morphology. The electroactivity of the nanocomposites was approved by cyclic voltammetry (CV) and impedance spectroscopy technique (EIS). The antioxidant ability and thermal property of the composites were further studied. Preliminary studies have evidenced the production of conductive nanocomposites with good thermal property and relatively good solubility in N-methyl 2-pyrrolidone (NMP), with the antioxidant activity reaching up to 80%.
- Thiacalix[4]arene,
- Nanocomposite,
- Polyaniline,
- Conductivity,
- Antioxidant
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
1. [1]
  Zhi-Peng Zhou , Xin Wei , Ming Yan , Zhi-Guo Wang , Rui Hong , Jia-Zhuang Xu . Multifunctional selenium nanoparticles/gelatin-based nanocomposite hydrogel adhesive for accelerated full-thickness wound healing. Chinese Chemical Letters, 2025, 36(9): 111400-. doi: 10.1016/j.cclet.2025.111400
2. [2]
  Qiang Luo , Jinfeng Sun , Zhibo Li , Bin Liu , Jianxun Ding . Thermo-sensitive poly(amino acid) hydrogel mediates cytoprotection through an antioxidant mechanism. Chinese Chemical Letters, 2025, 36(7): 110433-. doi: 10.1016/j.cclet.2024.110433
3. [3]
  Yiyang Zhang , Guangshu Yuan , Xiangkun Meng , Xu Zhang , Lei Yu . Promoting the catalytic activities of polyanilines for L-lactic acid condensation by calcium-doping: A biocompatible strategy. Chinese Chemical Letters, 2025, 36(12): 111069-. doi: 10.1016/j.cclet.2025.111069
4. [4]
  Fereshte Hassanzadeh-Afruzi , Mina Azizi , Iman Zare , Ehsan Nazarzadeh Zare , Anwarul Hasan , Siavash Iravani , Pooyan Makvandi , Yi Xu . Advanced metal-organic frameworks-polymer platforms for accelerated dermal wound healing. Chinese Chemical Letters, 2024, 35(11): 109564-. doi: 10.1016/j.cclet.2024.109564
5. [5]
  Xia Sun , Zixian Liang , Jiahao Zhang , Boxiang Peng , Bing Yu , Pei Liu , Biao Xiong , Jizhuang Wang , Yin Ning . Controlling the extent of nanoparticle occlusion within calcite crystals via surface chemistry engineering. Chinese Chemical Letters, 2025, 36(9): 111205-. doi: 10.1016/j.cclet.2025.111205
6. [6]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
7. [7]
  Quanyou Guo , Yue Yang , Tingting Hu , Hongqi Chu , Lijun Liao , Xuepeng Wang , Zhenzi Li , Liping Guo , Wei Zhou . Regulating local electron transfer environment of covalent triazine frameworks through F, N co-modification towards optimized oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(1): 110235-. doi: 10.1016/j.cclet.2024.110235
8. [8]
  Jiajie Gu , Jiaxiang Gu , Lei Yu . Selenium and Alzheimer's disease. Chinese Chemical Letters, 2025, 36(8): 110727-. doi: 10.1016/j.cclet.2024.110727
9. [9]
  Yangxia Chen , Wei Liu , Yinghui Liu , Sirui Li , Hongfang Liu , Shuoshan Li , Luo Ying , Rongyi Chen , Tianfeng Chen . Synergistic convergence of selenium and nanotechnology in dermatological therapeutics: Mechanistic insights and clinical prospects. Chinese Chemical Letters, 2026, 37(3): 111298-. doi: 10.1016/j.cclet.2025.111298
10. [10]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
11. [11]
  Liqiang Hao , Boyi Nie , Ziping Wan , Jianghua Qiu . The Role of SOD in Skincare: A Chemical Science Popularization Experiment. University Chemistry, 2025, 40(7): 241-248. doi: 10.12461/PKU.DXHX202409084
12. [12]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
13. [13]
  Yan Xin , Yunnian Ge , Zezhong Li , Qiaobao Zhang , Huajun Tian . Research Progress on Modification Strategies of Organic Electrode Materials for Energy Storage Batteries. Acta Physico-Chimica Sinica, 2024, 40(2): 2303060-0. doi: 10.3866/PKU.WHXB202303060
14. [14]
  Yibo Wang , Ruiyuan Xu , Binye Cao , Wanmei Li . Unlocking the Secrets of Battery Aging: Understanding the Life Cycle of Batteries. University Chemistry, 2026, 41(3): 330-335. doi: 10.12461/PKU.DXHX202503119
15. [15]
  Fangyan Zhang , Yuhan Li , Bowen He , Meng Lin , Ying Ma . Determination of Sodium Carbonate Content: A Conductometric Titration Approach. University Chemistry, 2026, 41(3): 373-380. doi: 10.12461/PKU.DXHX202505023
16. [16]
  Siyu Guo , Zhiye Chen , Jianzhao Liu , Yixuan Wang , Xinjian Feng , Shujin Li . Determination of Chloride Ion Content in Soy Sauce by Conductometric Precipitation Titration: A Recommended Undergraduate Chemistry Experiment. University Chemistry, 2026, 41(4): 372-379. doi: 10.12461/PKU.DXHX202502015
17. [17]
  Haiyang Peng , Zhipeng Xie , Shuiqing Lu , Da Zhang , Bin Yang , Feng Liang . Dual-functionality composites of polyaniline-coated oxidized carbon nanohorns: Efficient wave absorption and enhanced corrosion resistance. Chinese Chemical Letters, 2025, 36(6): 110818-. doi: 10.1016/j.cclet.2025.110818
18. [18]
  Xiujuan Qiao , Zhenying Xu , Zhen Wei , Yiting Hou , Fengxian Gao , Xijuan Yu , Xiliang Luo . A wearable electrochemical biosensor based on antifouling and conducting polyaniline hydrogel for cortisol detection in sweat. Chinese Chemical Letters, 2025, 36(11): 110884-. doi: 10.1016/j.cclet.2025.110884
19. [19]
  Husitu Lin , Shuangkun Zhang , Dianfa Zhao , Yongkang Wang , Wei Liu , Fan Yang , Jianjun Liu , Dongpeng Yan , Zhanpeng Wu . Flexible polyphosphazene nanocomposite films: Enhancing stability and luminescence of CsPbBr₃ perovskite nanocrystals. Chinese Chemical Letters, 2025, 36(4): 109795-. doi: 10.1016/j.cclet.2024.109795
20. [20]
  Siyu Cao , Yufei Shu , Li Wang , Qi Han , Meng Zhang , Mengxia Wang , How Yong Ng , Zhongying Wang . Controlling nanomaterial distribution and aggregation in thin-film nanocomposite membranes: Role of substrate pore's relative size with nanomaterials. Chinese Chemical Letters, 2025, 36(10): 110793-. doi: 10.1016/j.cclet.2024.110793

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1818)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142