Citation: İsmet Kaya, Murat Gül. SYNTHESIS, CHARACTERIZATION AND SOME PROPERTIES OF EPOXY RESINS CONTAINING AZOMETHINE BONDING[J]. Chinese Journal of Polymer Science, ;2013, 31(8): 1087-1095. doi: 10.1007/s10118-013-1293-9 shu

SYNTHESIS, CHARACTERIZATION AND SOME PROPERTIES OF EPOXY RESINS CONTAINING AZOMETHINE BONDING

İsmet Kaya ^, ,
Murat Gül

Corresponding author: İsmet Kaya,
Received Date: 21 August 2012
Revised Date: 18 October 2012

New epoxy resins were prepared from hydroxyl substituted Schiff base monomers in two steps. The first step is based on the synthesis of hydroxyl substituted Schiff base monomers via condensation reaction. The second step includes the reaction between Schiff base monomers with epichlorohydrine (EPC) to obtain epoxy resins. The structures of resulting compounds were confirmed by FTIR and 1H-NMR. TG-DTA and DSC measurements were made for thermal characterizations of the compounds. Chemical resistances of the cured epoxy-amine systems in acidic, alkaline and organic solvents were determined for coating applications. HCl (aqueous solution, 10%), NaOH (aqueous solution, 10%), DMSO, DMF, N-methylpyrrolidone, ethanol, THF and acetone were used for corrosion tests. Chemical resistance data show that the synthesized resins have good chemical resistance against various acid, alkaline and common organic solvents.
- Epoxy resin,
- Thermal analysis,
- Poly(imine)s
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