Citation: Yang Zou, Yuan Liu, Jin-gui Qin, Chu-luo Yang. SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STAR-SHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE[J]. Chinese Journal of Polymer Science, ;2013, 31(6): 938-945. doi: 10.1007/s10118-013-1286-8 shu

SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STAR-SHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE

Received Date: 17 January 2013
Revised Date: 3 February 2013

Fund Project: This work was financially supported by the National Science Fund for Distinguished Young Scholars of China (No. 51125013).

Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.
- Star-shaped molecules,
- Hexakis(fluoren-2-yl)benzene,
- Oligothiophene,
- Electropolymerization
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