Citation: Zheng-guo Cai, Hai-hui Su, Takeshi Shiono. PRECISE SYNTHESIS OF OLEFIN BLOCK COPOLYMERS USING A SYNDIOSPECIFIC LIVING POLYMERIZATION SYSTEM[J]. Chinese Journal of Polymer Science, ;2013, 31(4): 541-549. doi: 10.1007/s10118-013-1250-7 shu

PRECISE SYNTHESIS OF OLEFIN BLOCK COPOLYMERS USING A SYNDIOSPECIFIC LIVING POLYMERIZATION SYSTEM

Received Date: 1 November 2012
Revised Date: 28 November 2012

This feature article summarizes the synthesis of novel olefin block copolymers using fast syndiospecific living homo- and copolymerization of propylene, higher 1-alkene, and norbornene with ansa-fluorenylamidodimethyltitanium-based catalyst according to the authors' recent results. The catalytic synthesis of monodisperse polyolefin and olefin block copolymer was also described using this living system.
- Single-site catalyst
1. [1]
1. [1]
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2. [2]
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3. [3]
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7. [7]
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8. [8]
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14. [14]
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15. [15]
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16. [16]
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19. [19]
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