Citation:
Ou Zhang, Hong-mei Yu, Li-min Lu, Yang-ping Wen, Xue-min Duan, Jing-kun Xu. POLY(THIOPHENE-3-ACETIC ACID)-PALLADIUM NANOPARTICLE COMPOSITE MODIFIED ELECTRODES FOR SUPERSENSITIVE DETERMINATION OF HYDRAZINE[J]. Chinese Journal of Polymer Science,
;2013, 31(3): 419-426.
doi:
10.1007/s10118-013-1230-y
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A promising electrochemical sensor was fabricated by electrodeposition of Pd nanoparticles (PdNPs) on poly(thiophene-3-acetic acid) (PTAA)-modified glassy carbon electrode (GCE), forming a PdNPs/PTAA composites-modified GCE (PdNPs/PTAA/GCE). Scanning electron microscope (SEM) and electrochemical techniques were used for the characterization of these composites. It was found that the PdNPs/PTAA layer was very uniform. Electrochemical experiments showed that this proposed PdNPs/PTAA composites-modified electrode exhibited excellent electrocatalytic activity towards the oxidation of hydrazine. Under the optimum conditions, the proposed sensor can be applied to the quantification of hydrazine with a wide linear range from 8.0?10-9 mol/L to 1.0?10-5 mol/L with a low detection limit of 2.67?10-9 mol/L. The experiment results also showed that the sensor exhibited good reproducibility and long-term stability, as well as high selectivity with no interference from other potential competing species.
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Keywords:
- Sensor
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