多铌氧簇聚物是多金属氧簇聚物的重要组成部分，具有丰富多样的结构类型，在碱催化、光催化产氢等方面具有广泛的应用前景，吸引了越来越多化学工作者的关注。本文系统地综述了主族元素（ⅢA/ⅣA/ⅤA/ⅥA族）为杂原子的杂多铌氧簇聚物和过渡元素（V/Fe/Cu）为杂原子的杂多铌氧聚合物的研究进展，主要包括化合物的合成策略、结构调控、性质及应用的探索。此外，对当前杂多铌氧簇聚物的发展所面临的挑战进行了总结，并对其后续的发展进行了展望。

Herein, the positively charged two-dimensional (2D) porous silica (PSN⁺) nanosheet was obtained by modifying the 2D silica obtained from acid-etched 2D vermiculite, and then the PSN⁺ was used as the filler of polyethylene oxide (PEO)-based solid polymer electrolytes (SPEs). Given the abundant positive charges, PSN⁺ effectively binds with the anions dissociated from lithium salts, thereby promoting lithium-ion transport and achieving a decent lithium-ion transference number. At 50 ℃, the PSN⁺-based SPEs demonstrated a higher ionic conductivity of 7.5×10^-5 S·cm^-1, lithium-ion transference number of 0.30, and a stable voltage window of 4.41 V. Consequently, the as-assembled LiFePO₄||Li batteries delivered excellent initial discharge specific capacity of 155.7 mAh·g^-1 at 0.2C with 97.1% capacity retention after 100 cycles at 50 ℃.