甘蓝色素稳定性研究
付世涛, 张剑鸣, 曹灿灿, 汪志慧, 秦超然, 张建, 熊辉
【大学化学】doi: 10.3866/PKU.DXHX202401059
本文以紫甘蓝蔬菜为原料,进行了pH、金属离子和各种食品添加剂等一系列稳定性分析,探索紫甘蓝色素的最佳存储和使用环境。研究表明,紫甘蓝色素对pH敏感,随着pH增大,色素保留率逐渐减小;不同金属离子对紫甘蓝色素的稳定性也有影响,Fe3+会破坏紫甘蓝色素的结构,降低稳定性,保留率仅为8.68%;而Ca2+能提高其稳定性。添加剂蔗糖也可提高其稳定性,其中20 g·L-1的蔗糖水溶液可将保留率提升至119.48%;而食盐、苯甲酸钠和山梨酸钾均会降低其稳定性。
关键词: 紫甘蓝色素, 影响因素, 稳定性
Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials
Huirong LIU, Hao XU, Dunru ZHU, Junyong ZHANG, Chunhua GONG, Jingli XIE
【无机化学学报】doi: 10.11862/CJIC.20240066
Two new viologen-polyoxometalate hybrid crystalline materials: (MV)2[HPW2W10O40] ·2H2O (1) and (EV)2[Mo8O26] (2) have been synthesized by using the cations of 1, 1'-dimethyl-4, 4'-bipyridinium dichloride (methyl viologen, MV) and 1, 1'-diethyl-4, 4'-bipyridinium dibromide (ethyl viologen, EV) as the electron acceptors, and the electron-rich polyoxometalate anions as the electron donors. The structures of compounds 1 and 2 have been determined by single-crystal X-ray crystallography. Hydrogen bond interactions exist between the cations and the anions in 1 and 2. Interestingly, 2 has a photochromic performance with a light response time within 1 min. The photochromic mechanism of compound 2 has been investigated by solid-state diffuse reflection, electron paramagnetic resonance and theoretical calculation. 1 and 2 show good catalytic performance in the photocatalytic degradation of several organic dyes (methylene blue, pararosaniline hydrochloride and rhodamine 6G).
关键词: viologen, polyoxometalate, photochromism, photocatalysis

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