Citation: Jun Min HUANG, Hui CHEN, Ru Yu CHEN. A Novel Fused Phosphorus Heterocycle:4-(1', 2', 3', 4'-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2'-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative[J]. Chinese Chemical Letters, ;2002, 13(2): 125-128. shu

A Novel Fused Phosphorus Heterocycle:4-(1', 2', 3', 4'-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2'-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative

Institute of Elemento-Organic Chemistry, National Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 11 June 2001

Fund Project: The project was supported by the National Natural Science Foundation of China and Foundation for University Key Teacher by the Ministry of Education.

The first example of fused phosphorus heterocyclic 4-[l'-(β-bromoethyl)-4'-oxo-3'-prop yl-1', 2', 3', 4-tetrahydro-1, 3, 2-benzodiazaphosphorin-2'-sulfide]-1, 2, 3, 4, 4a, 4b, 5, 6-octahydro-6-oxo-5-propyl-3, 4b, 4a-thiazphosphaphenanthridine 4a, 2'-dioxide was synthesized in excellent yield by refluxing a mixture of 1-(2-bromoethyt)-2, 3-dihydro-3-propyl-l, 3, 2-benzodiazaphos phorin-4(1H)-one 2-oxide with carbon disulfide in benzene in the presence of triethylamine.
- Synthesis,
- [3,
- 4b,
- 4a] thiazphosphaphenanthridine
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