Citation: Shu Hua LI, Wei Dong LI, Yu Lin LI. The Total Synthesis of 14-Deoxycrassin and Pseudoplexaurol:A Convergent Synthesis of Cyclization Precursor[J]. Chinese Chemical Letters, ;2002, 13(9): 820-823. shu

The Total Synthesis of 14-Deoxycrassin and Pseudoplexaurol:A Convergent Synthesis of Cyclization Precursor

National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 12 December 2001

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Grant No.20072012) and the Foundation for University Key Teacher by the Ministry of Education of China.

The synthesis of epoxy aldehyde 4, a cyclization precursor for the total synthesis of 14-deoxycrassin and pseudoplexaurol, starting from geraniol in a convergent and stereoselective manner, is described.
- Cembranolides,
- total synthesis,
- 14-deoxycrassin,
- pleaxaurol
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