Citation: Zheng Ping FANG, Hai Tang YANG, Qian Jiang MIAO, Guo Ping CAI. Synthesis of Methyl-(γ-chloropropyl)dichlorosilane Catalyzed by Silica-supported Karstedt-type Catalyst[J]. Chinese Chemical Letters, ;2006, 17(9): 1155-1158. shu

Synthesis of Methyl-(γ-chloropropyl)dichlorosilane Catalyzed by Silica-supported Karstedt-type Catalyst

1.
Institute of Polymer Composites, Zhejiang University, Hangzhou 310027;
2.
Key Laboratory of Macromolecule Synthesis and Functionalization(Zhejiang University), Ministry of Education, Hangzhou 310027

Received Date: 6 March 2006

Fund Project: Financial support from the National Natural Science Foundation of China (No. 50473036) is gratefully acknowledged.

Methyl-(γ-chloropropyl)dichlorosilane was synthesized under the catalysis of a silicasupported Karstedt-type catalyst. By orthogonal experimental design method, the optimum reaction parameters such as reactants ratio, reaction temperature and time, and the dosage of catalyst, were determined. At the optimum reaction condition the product yield reached 78.42%, which is higher than that reported in the literatures.
- Methyl-(γ-chloropropyl)dichlorosilane,
- silica-supported Karstedt-type catalyst,
- hydrosilylation,
- synthesis
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