Citation: Wen Qian YANG, Shi Zhi CHEN, Liang HUANG. Diels-Alder Reactions of 3-Carboethoxy-and 3-Carbonitrile-2-Cyclohexen-1-one[J]. Chinese Chemical Letters, ;1998, 9(3): 233-234. shu

Diels-Alder Reactions of 3-Carboethoxy-and 3-Carbonitrile-2-Cyclohexen-1-one

Institute of Materia Medica, Chinese Academy of Medical Sciences & Peking Union Medical College Beijing 100050

Received Date: 5 November 1997

Fund Project: This project was supported by the National Natural Science Foundation of China.

Aluminum chloride induced Diels-Alder reactions of 3-carboethoxy-and 3-carbonitrile-2-cyclohexen-1-one with cyclopentadiene, isoprene and (E)-piperylene were described. The stereochemistry of the adducts were confirmed by 2D-NMR spectroscopy and isomerization reactions.
- Diels-Alder reaction,
- base-induced isomerization
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