Citation: Tian Ming YAO, Xian Fa SHI, Xiao Zeng YOU. MAGNETIC INVESTIGATION OF THE NICKEL COMPLEXES OF MULTI-SULFUR 1.2-DITHIOLATES[J]. Chinese Chemical Letters, ;1996, 7(7): 685-686. shu

MAGNETIC INVESTIGATION OF THE NICKEL COMPLEXES OF MULTI-SULFUR 1.2-DITHIOLATES

a Department of Chemistry, Tongji University, Shanghai 200092;
b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093

Received Date: 27 June 1995

The magnetic susceptibility of[Bu₄N][Ni (MEDT)₂]and[BU₄N] [Ni (PHDT) ₂] (MEDT:5-methyl-6-hydro-1, 4-dithiin-2, 3-dithiolate, PHDT:5-phenyl-6-hydro-1, 4-dithiin-2, 3-dithiolate) was measured in the temperature range of 75-300K. The magnitude of magnetic moments is consistent with a doublet state arising from Ni (Ⅲ). Antiferromagnetic properties were discussed in consideration of molecular structure.
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