Citation: Min Min SHI, Hong Zheng CHEN, Jing Zhi SUN, Jian YE, Mang WANG. Effect of Fluorination on Aggregate Structure of Perylene Diimide[J]. Chinese Chemical Letters, ;2004, 15(5): 575-578. shu

Effect of Fluorination on Aggregate Structure of Perylene Diimide

Department of Polymer Science and Engineering, State Key Lab of Silicon Materials, Zhejiang University, Hangzhou 310027

Received Date: 7 April 2003

Fund Project: The authors acknowledge the financial support of the NNSFC (No. 50173021, 50225312) and the fund for the century scholar training project from the Education Department of China.

The effect of fluorination on the aggregate structure of a novel fluorinated perylene diimide, N, N'-diperfluorophenyl-3, 4, 9, 10-perylenetetracarboxylic diimide 1, was investigated by UV-Vis absorptions and the conformation simulations from AM1 semi-empirical quantum mechanics modeling. The results showed that in the solid film 1 molecules stacked with the perfluorinated phenyl groups straightly over or below the perylene cores of the adjacent 1 molecules.
- Fluorination,
- perylene diimide,
- aggregate structure,
- absorption
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