Citation: Wen XU, Qi FANG, Gang XUE, Wen Tao YU, Hong Yu CHEN, Guo Qun LIU, Wei XU, Cui Ying XU, De Qing ZHANG, Dao Ben ZHU. Synthesis, Structure and Conductivity of (PyH)[Ni(dmit)₂]₂[J]. Chinese Chemical Letters, ;2003, 14(10): 1089-1092. shu

Synthesis, Structure and Conductivity of (PyH)[Ni(dmit)₂]₂

Wen XU ¹ ,
Qi FANG ¹ ,
Gang XUE ¹ ,
Wen Tao YU ¹ ,
Hong Yu CHEN ¹ ,
Guo Qun LIU ¹ ,
Wei XU ² ,
Cui Ying XU ² ,
De Qing ZHANG ² ,
Dao Ben ZHU ²

1.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2.
Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080

Received Date: 21 October 2002

Fund Project: This work was supported by the National Natural Science Foundation of China (No.20172034) and the Key Laboratory of Organic Solids, the Chinese Academic of Sciences.

A new molecular conductor (PyH)[Ni(dmit)₂]₂(dmit=4, 5-dimercapto-1, 3-dithiole-2-thione) has been prepared and its crystal structure has been determined. Crystallographic parameters for (PyH)[Ni(dmit)₂]₂:C₁₇H₆NNi₂S₂₀;triclinic system;P-1 space group;a=5.9227 (4), b=8.2279 (6), c=16.7535 (9)Å, α=90.233 (5)°, β=92.107 (6)°, γ=104.654 (6) °;V=789.25 (9) Å³;Z=1;D_c=2.068 g/cm³;F(000)=491. The conductivity at one direction on (001) plane at room temperature was measured to be 0.13 Ω^-1·cm^-1. The resistivity-temperature curve in the temperature range of 90~290 K shows that this compound behaves as a semiconductor.
- Molecular conductor,
- synthesis,
- electrical conductivity,
- semiconductor,
- structure
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