Citation: Pei Pei SUN, Ya Ping XIAO, Bao Chuan SHI. Bismuth Mediated Organic Reaction:A Convenient Method for the Synthesis of Allylic (Benzylic) Selenides and α-Organylselenocarbonyl Compounds in Aqueous Media[J]. Chinese Chemical Letters, ;2000, 11(12): 1037-1040. shu

Bismuth Mediated Organic Reaction:A Convenient Method for the Synthesis of Allylic (Benzylic) Selenides and α-Organylselenocarbonyl Compounds in Aqueous Media

Department of Chemistry, Nanjing Normal University, Nanjing 210097

Received Date: 1 June 2000

In the presence of BiCl₃/Al or BiCl₃/Fe, in THF-H₂O, allylic (benzylic) bromides or α-bromoketones react with diorganyl diselenides to give allylic (benzylic) selenides or α-organylselenocarbonyl compounds respectively in moderate to good yields.
- Bismuth,
- allylic (benzylic) selenides,
- α-organylselenocarbonyl compounds,
- synthesis
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