Citation: Guo Dong ZHENG, Yu Wen LIU, Qing Da AN, Xi Zhang CAO. ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYZED BY METALLOPORPHYRINS(Ⅲ)--EFFECTS OF AXIAL LIGANDS ON CATALYTIC ACTIVITY OF CoTPP[J]. Chinese Chemical Letters, ;1992, 3(5): 355-356. shu

ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYZED BY METALLOPORPHYRINS(Ⅲ)--EFFECTS OF AXIAL LIGANDS ON CATALYTIC ACTIVITY OF CoTPP

a Department of Chemistry Jilin University Changchun 130023;
b To whom all correspondence should be addressed;
c Present adress;Dalian Institute of Light Industry

Received Date: 18 December 1991

Fund Project: This work is supported by the National Natural Science Foundation of China.

The effects of peptides, amino acids and organic bases as an axial ligand on reaction ac-tivities in the electrocarboxylation of benzyl chloride with CO₂ catalyzed by CoTPP are reported.The imidazole organic base, peptide containing —SH and amino acid containing imidazolyl en-hance the catalytic activity.The effect of imidazole amounts on the catalytic activity of CoTPP isstudied
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