Citation: Cheng Feng YE, Ze Fu ZHANG, Wei Min LIU. A Novel Synthesis of Some Hexasubstituted Cyclotriphosphazenes[J]. Chinese Chemical Letters, ;2001, 12(4): 301-304. shu

A Novel Synthesis of Some Hexasubstituted Cyclotriphosphazenes

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Received Date: 30 September 2000

Fund Project: We are grateful to the National Natural Science Foundation of China (grant NO. 59825116) and Chinese Academy of Sciences for the financial support.

Some known and new hexaaryloxyphosphazene N₃P₃ (O-C₆H₄-R)₆] (R=H, CH₃, OCH₃, C(CH₃)₃, CHO, F, C₆H₅COOR, etc) were readily obtained with ca. 70% isolated yield in refluxing acetonitrile in the presence of anhydrous potassium phosphate. All compounds were characterized by means of elemental analysis,¹H-NMR,³¹P-NMR spectroscopy.
- Phosphazene,
- cyclotriphosphazene,
- phenols,
- potassium phosphate.
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