Citation: Qian WANG, Hai Yan LU, Yu Fen ZHAO. Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester[J]. Chinese Chemical Letters, ;1997, 8(12): 1017-1018. shu

Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester

Bioorganic Phosphorus Chemistry Laboratory, Department of Chemistry Tsinghua University, Beijing 100084

Received Date: 20 August 1997

Fund Project: We thank the financial support of the National Natural Science Foundation of China and the National Science and Technology Committee.

N-Trimethylsilylvaline trimethylsilyl ester Ⅱa,N-triethylsilylvaline triethylsilyl ester Ⅱb and N-tert-butyldimethylsilylvaline tert-butyldimethylester Ⅱc showed evidently different reactivities with O,O'-phenylenephosphorylchloride.The formation speed of the final spiro-bicyclic pentacoordinated phosphorus compounds Ⅳ depends on the intramolecular transfer ability of the silyl oiety crucially.
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