Citation: Zhi Gang YIN, De Feng ZHAO. A New Technique of Synthesizing 10-Hydroxy-5-methyl-5,10-dihydrophenophosphazine 10-Oxide[J]. Chinese Chemical Letters, ;2003, 14(4): 347-350. shu

A New Technique of Synthesizing 10-Hydroxy-5-methyl-5,10-dihydrophenophosphazine 10-Oxide

Zhi Gang YIN ^1,2, ,
De Feng ZHAO ¹

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012;
2.
Chemical Engineering Department, Zhengzhou Institute of Light Industry, Zhengzhou 450002

Received Date: 24 May 2002

Fund Project: The authors would like to acknowledge support from the National Natural Science Foundation of China(29972006), especially to express the deep appreciation to Professor Q. J. Peng and Miss K. Jin from our laboratory for their assistance in performing structural inspection and calculating coupling constants, which made them have to contribute their holidays.

10-Hydroxy-5-methyl-5, 10-dihydrophenophosphazine 10-oxide (1) was prepared by a new technique of treating 10-methoxy-5,10-dihydrophenophosphazine 10-oxide (2) with an equivalent of NaH in anhydrous DMF, and then at 120℃ for 3~4 h, which not only avoided poisonous and expensive methyl iodide used in literature, but made the consumption of NaH greatly decrease as well. The possible reaction mechanism was also described. The chemical structure of 1 was confirmed by IR, NMR, and mass spectroscopy.
- 10-Dihydrophenophosphazine,
- synthesis,
- structure identification
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