Citation: Bao Wen ZHANG, Robert S. H. LIU. EFFECT OF HYDROGEN BONDING ON DIRECTION OF PHOTOISOMERIZATION OF RETINOIDS:THE ORIGIN OF THE SOLVENT POLARITY EFFECT.[J]. Chinese Chemical Letters, ;1991, 2(1): 9-12. shu

EFFECT OF HYDROGEN BONDING ON DIRECTION OF PHOTOISOMERIZATION OF RETINOIDS:THE ORIGIN OF THE SOLVENT POLARITY EFFECT.

Department of Chemistry, 2545 The Mall University of Hawaii, Honolulu, HI 96822 U. S. A

Received Date: 14 December 1990

Fund Project: The work was supported by grants from U.S.Public Health Services (DK-17806) and the Natural Science Foundation (CHE-16500).

Studies of direction of photoisomerization of retinal, retinonitrile, α-retinonitrile and a trienenitrile analog in different solvents with varying wave-lengths of excitation and reaction temperature led to the conclusion that the well known solvent dependent photochemistry of retinoids is due to selective excitation of the hydrogen bonded species.
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