Citation: Xue Ning JIANG, Dong XU, Duo Rong YUAN, Wen Tao YU, Meng Kai LU, Shi Yi GUO, Guang Hui ZHANG, Qi FANG. Synthesis, Structure and Properties of Tetrakis (thiourea) mercury (II) Tetrakis (thiocyanato-N) zinc (II)[J]. Chinese Chemical Letters, ;2001, 12(3): 279-282. shu

Synthesis, Structure and Properties of Tetrakis (thiourea) mercury (II) Tetrakis (thiocyanato-N) zinc (II)

Institute of Crystal Materials and State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100

Received Date: 25 August 2000

Fund Project: This work was supported by the National Natural Science Foundation of China (No.69890230 and No.69778023) and the Scientific Research Foundation for Outstanding Young Scientist of Shandong Province of China.

A new nonlinear optical complex crystal tetrakis (thiourea) mercury (II) tetrakis (thiocyanato-N) zinc (II) was synthesized and its structure was determined. It belongs to the tetragonal system, I4 space group. The crystal structure consists of discrete[Zn(SCN)₄]^2- anions and[Hg(NH₂CSNH₂)₄]²⁺ cations with slightly distorted coordination tetrahedra ZnN₄ and HgS₄. The second harmonic generation (SHG) of the crystal was found to be superior to that of urea.
- TMTZ crystal,
- synthesis,
- structure,
- properties
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