Citation: Xiang Dong WANG, Bao Wen ZHANG, Jian Wei BAI, Yi CAO, Xu Rui XIAO, Jing Mei XU. A NEW ARTIFICIAL PHOTOSYNTHESIS COMPOUND FOR PHOTOELECTRIC CONVERSION[J]. Chinese Chemical Letters, ;1991, 2(4): 281-284.
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A new triad model compound porphyrin-viologen-carbazole was synthesized to mimic photosynthesis.A mechanism including photoinduced electron transfer and two-step charge separation was suggested.This triad compound was easy to form LB film and rather high photodriven voltage and current were obtained with only one layer of LB film on the surface of SnO2 conductive glass.
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