Citation: Yu Lin LI, Xin CHEN, Si Chang SHAO, Tong Shuang LI. TOTAL SYNTHESIS OF(-)-3-OXOEUDESMA-1,4,11(13)-TRIEN-7αH-12-OIC ACID[J]. Chinese Chemical Letters, ;1993, 4(2): 105-106. shu

TOTAL SYNTHESIS OF(-)-3-OXOEUDESMA-1,4,11(13)-TRIEN-7αH-12-OIC ACID

State Key Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 10 August 1992

Fund Project: This project was supported by the National Natural Science Foundation of China.

The first total synthesis of(-)-3-oxoeudesma-1,4,11(13)-trien-7αH-12-oic acid 1 has been described.The key step is one-pot reaction involving dehydrogenation and allylic oxidationwith selenium dioxide.
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