Citation: Guan-qun Zhong, Qing-hua Duan, Kui-lin Deng, Ai-qin Zhang, Ping Xie, Hai-liang Zhang, Rong-ben Zhang. H-Bonding Self-Assembled Template-Controlled Synthesis of A Novel Soluble and Reactive Amide-Bridged Ladderlike Polyhydrosiloxane[J]. Chinese Journal of Polymer Science, ;2006, 24(1): 67-72. shu

H-Bonding Self-Assembled Template-Controlled Synthesis of A Novel Soluble and Reactive Amide-Bridged Ladderlike Polyhydrosiloxane

Received Date: 25 January 2005
Revised Date: 20 March 2005

A novel soluble and reactive amide-bridged ladderlike polyhydrosiloxane (ALPHS) was first synthesized by an amido H-bonding self-assembled template. ALPHS with molecular weight = 18300 has very highly ordered ladderlike structure, which was confirmed by a sharp resonance absorption peak of [―Si(H)O2/2 ] moiety with the half peak width 1/2 < 0.5 in 29Si-NMR spectrum. Presence of the reactive Si―H groups gives ALPHS an opportunity to further derive a variety of functional polymers by versatile Si―H reactions such as hydrosilylation, condensation, and so on.
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