Citation: Guang Xiang LIU, Xiao Ming REN, Heng XU, Chuan Yi TANG, Gen Hua WU, You Cun CHEN. Crystal Structures and Magnetic Properties of Two New Schiff Base Complexes[J]. Chinese Chemical Letters, ;2004, 15(9): 1105-1108. shu

Crystal Structures and Magnetic Properties of Two New Schiff Base Complexes

Department of Chemistry, Anqing Normal College, Anqing 246003

Received Date: 28 July 2003

Fund Project: The work was supported by the National Natural Science Foundation (No.20171001), the Natural Science Foundation of Anhui Province (No.01012038) and the Natural Science Foundation of Anhui Province Education Commission (No.2003kj253, 2003jql53).

Two new Schiff base complexes,[NiL]ClO₄ 1 and [CuL]ClO₄·0.5H₂O 2, were synthesized and characterized, where L is the 1:1 condensation product of salicylaldehyde and diethylenetriamine. Their crystal structures and magnetic properties were determined and investigated. The H-bonding interactions concern just in neighbor cation and anion, do not extend into network for both 1 and 2. The temperature dependence of the magnetic susceptibilities (2-300K) showed that 1 is diamagnetism and 2 is paramagnetism with weak antiferromagnetic exchange interactions between adjacent spin carriers, no magnetic ordering taking place in these two complexes.
- Schiff base complex,
- crystal structure,
- H-bonding interaction,
- magnetic property
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