Citation: Peng GUO, Jin Chu LIU, Zhi Qiang FANG, Ai Qiao MI, Yao Zhong JIANG. THE ASYMMETRIC ALKYLATIONS OF CHIRAL TRANSITION METAL COMPLEXES OF (+)-CAMPHOR IMINE[J]. Chinese Chemical Letters, ;1991, 2(3): 201-204. shu

THE ASYMMETRIC ALKYLATIONS OF CHIRAL TRANSITION METAL COMPLEXES OF (+)-CAMPHOR IMINE

Chengdu Institute of Organic Chemistry, Academia Sinica, Chengdu 610015

Received Date: 6 October 1990

Fund Project: This work was supported by the National Natural Science Foundation of China.

The asymmetric alkylations of chiral transition metal complexes derived from (+)-camphor and 2-aminomethyl-6-methylpyridine were examined under mild conditions. The formation of the complexes 2 is conductive to the enhancement of diastereoselectivity in the alkylations at room temperature.
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