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Citation: Fu Xiangkai, Kang Wei, Wen Shuying, Deng Chuanyue. Alkylation Reaction Catalyzed with Amorphous Zirconium(Diphenylphosphinate-hydrogen phosphate)-Ferric Chloride Complex[J]. Chinese Journal of Applied Chemistry, ;1995, 12(6): 47-49. shu

Alkylation Reaction Catalyzed with Amorphous Zirconium(Diphenylphosphinate-hydrogen phosphate)-Ferric Chloride Complex

College of Chemistry and Chemical Engineering, Southwest-China Normal University, Chongqing 630715

Received Date: 7 March 1995
Revised Date: 21 August 1995

Amorphous zirconium(diphenylphosphinate-hydrogen phosphate)-ferric chloride complex Zr(HPO₄)_1.5[O₂P(C₆H₅)₂]·[FeCl₂(OH)] was prepared. The complex is low hy-groscopic,not fumy and stable in air. The complex shows fairly good catalytic activity for Friedel-Crafts alkylation reaction of aromatic hydrocarbons with alkyl halides in liquid phase. The advantages of the reaction are: mild reaction condition,high yield of products,easy operation,simple after-treatment,and many times reuse of the catalyst.
- zirconium diphenylphosphinate-hydrogen phosphate,
- ferric chloride,
- complex,
- alkyl halide,
- Friedel-Crafts alkylation
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