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Citation: Zai Ming ZHU, Qun LIU, Zhi Yun YANG. α-OXOKETENE CYCLIC DITHIOACETAL CHEMISTRY(XⅢ)-THE ETHERIFYING REACTION ON THE ADDUCTS OF ALIPHATIC α-OXO KETENE CYCLIC DITHIOACETALS WITH ALLYL MAGNESIUM BROMIDE[J]. Chinese Chemical Letters, ;1993, 4(9): 759-762. shu

α-OXOKETENE CYCLIC DITHIOACETAL CHEMISTRY(XⅢ)-THE ETHERIFYING REACTION ON THE ADDUCTS OF ALIPHATIC α-OXO KETENE CYCLIC DITHIOACETALS WITH ALLYL MAGNESIUM BROMIDE

Department of Chemistry, Northeast Normal University, Chang Chun, 130024

Received Date: 15 March 1993

Aliphatic α-oxo ketene cyclic dithioacetals 1 were reacted with allyl magnesium bromide to afford the 1, 2-addition products 2.Catalyzed by boron trifluoride etherate, the adducts 2 were etherified by methanol to afford the corresponding methyl ethers 3.This process provides a new method for the protection of the acid sensitive hydroxyl group in 2 under mild condition.
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