Citation: Jing Song YOU, Xiao Qi YU, Xiao Ling ZHANG, Ru Gang XIE. Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles[J]. Chinese Chemical Letters, ;1998, 9(4): 335-337. shu

Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles

Department of Chemistry, Sichuan University, Chengdu 610064

Received Date: 11 November 1997

Fund Project: The project (No.29502008) is supported by the National Natural Science Foundation of China.

A series of chiral lipophilic Cu(Ⅱ) complexes were investigated as catalysts for the enantioselective hydrolysis of R(S)-p-nitrophenyl N-dodecanoyl-phenylalaninate in micelles. The highest enantioselectivity (k_R/k_S=7.81) was observed in a mixed micellar system composed of 1-Cu(Ⅱ) and Brij35.
- micelle,
- chiral metallomicelle,
- enantioselective hydrolysis
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