Citation: Xiu Zhong ZHOU, Huai Lin SUN, Chui Hua KONG, Ru Ji WANG, Hong Gen WANG. SYNTHFESIS,STRUCTURE AND RFACTION OF TETRAMETHYL-DISILANDIYL DICYCLOPENTADIENYL TETRACARBONYL DI-IRON[J]. Chinese Chemical Letters, ;1993, 4(4): 367-368. shu

SYNTHFESIS,STRUCTURE AND RFACTION OF TETRAMETHYL-DISILANDIYL DICYCLOPENTADIENYL TETRACARBONYL DI-IRON

Department of Chemistry, Nankai University, Tianjin 300071

Received Date: 9 September 1992

The title compounds (Me₂SiSiMe₂) (η-RC₅H₃)Fe(CO)(μ-CO) ₂(R:H(1a),Me(1b)) were prepared by heating a solution of RC₅H₄ (Me₂SiSiMe₂) C₅H₄R and Fe(CO)₅ in xylene atreflux. (1a) and (1b) can convert into their isomers Me₂Si (η-RC₃H₃) Fe(CO)₂ ₂(R:H(2a),Me(2b)) under the reaction conditions.The crystal and molecular structures of (1a), (2a) and (2b) were determined by X-ray diffraction.
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