Citation: Yi Yi, Xing-he Fan, Yong-feng Zhao, Xiao-fang Chen, Xin-hua Wan, Qi-feng Zhou. ATOM TRANSFER RADICAL POLYMERIZATION OF 2,5-BIS[(4-HEXYLOXYPHENYL)OXYCARBONYL]STYRENE[J]. Chinese Journal of Polymer Science, ;2005, 23(3): 249-253. shu

ATOM TRANSFER RADICAL POLYMERIZATION OF 2,5-BIS[(4-HEXYLOXYPHENYL)OXYCARBONYL]STYRENE

Corresponding author: Xing-he Fan,
Received Date: 11 February 2004
Revised Date: 12 March 2004

A side-on liquid crystalline monomer, 2,5-bis[(4-hexyloxyphenyl)oxycarbonyl]styrene) (HPCS), was successfully polymerized via atom transfer radical polymerization (ATRP). The polymerization was catalyzed by CuBr/PMDETA in chlorobenzene at 90℃ with (1-bromoethyl)benzene as the initiator. The polymers have narrow MWD. It is the second example of mesogen-jacketed liquid crystalline polymer (MJLCP) prepared by ATRP.
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