Citation: Pang CHENG, Dai Zheng LIAO, Shi Ping YAN, Zong Hui JIANG, Geng Liu WANG. PARAMAGNETIC AND DIAMAGNETIC DICOPPER(Ⅱ) COMPLEXES WITH DI-SCHIFF BASE DERIVED FROM 2-HYDROXY-1-NAPHTHALDEHYDE AND1, 3-DIANINO-2-PROPANOL[J]. Chinese Chemical Letters, ;1995, 6(7): 641-644. shu

PARAMAGNETIC AND DIAMAGNETIC DICOPPER(Ⅱ) COMPLEXES WITH DI-SCHIFF BASE DERIVED FROM 2-HYDROXY-1-NAPHTHALDEHYDE AND1, 3-DIANINO-2-PROPANOL

Department of Chemistry, Nankai University, Tianjin 300071

Received Date: 5 January 1995

Fund Project: This work was supported by National Natural Science Foundation of China.

Four new binuclear copper(Ⅱ)complexes[Cu₂(L)(μ-X)]have been synthesized and characterized, where X=C₆H₅COO(1), C₂H₅COO(2), pyrazolate(C₃H₃N₂)(3)and 1, 3-N₃(4).The ligand H₃L is a 2:1 Schiff base derived from 2-hydroxy-1-naphthaldehyde and 1, 3-diamino-2-propanol.The variable temperature magnetic analyses show that complexes(1), (2)and(3)are paramagnetic with 2J=-158~-188 cm^-1, and complex(4)is diamagnetic with|2J|>1000 cm^-1.
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