Citation: Shu-hao Qin, Jie Yu, Min He, Wei Yan. EFFECTS OF INTERPARTICLE DISTANCE, TEMPERATURE AND INTERFACIAL ADHESION ON BRITTLE-DUCTILE TRANSITION FOR NYLON 6/ABS BLENDS[J]. Chinese Journal of Polymer Science, ;2009, 27(5): 719-728. shu

EFFECTS OF INTERPARTICLE DISTANCE, TEMPERATURE AND INTERFACIAL ADHESION ON BRITTLE-DUCTILE TRANSITION FOR NYLON 6/ABS BLENDS

Received Date: 14 August 2008
Revised Date: 2 December 2008

The toughness of blends composed of nylon 6 and acrylonitrile-butadiene-styrene (ABS) compatibilized by using styrene-maleic anhydride (SMA) as a compatibilizer was measured over a wide temperature region. Results reveal that the combining effects of particle size and volume fraction of ABS on the toughness of nylon 6/ABS/SMA blends can be described through plotting brittle-ductile transition of the impact strength versus the interparticle distance (ID) on the assumption that ABS domains relieve the triaxial tension via internal cavitation or interfacial debonding. Moreover, the effect of interfacial adhesion on fracture behavior of nylon 6/ABS/SMA blends strongly depends upon the testing temperature. The difference of relation amomg temperature, fracture behavior and interfacial adhesion can be understood in terms of the deformation mechanisms, i.e. in the case of poor interfacial adhesion, the toughness lies on whether debonding existing at the interface relieves triaxial tension or not. It is believed that for good interfacial adhesion, internal cavitation followed by matrix shear yielding is a predominant factor for toughening. Furthermore, the fracture surface of these blends was probed to elucidate how interfacial adhesion affected the impact strength of the blends.
1. [1]
  Dian-Xue Ma , Yu-Wu Zhong . Achieving highly-efficient room-temperature phosphorescence with a nylon matrix. Chinese Journal of Structural Chemistry, 2024, 43(9): 100391-100391. doi: 10.1016/j.cjsc.2024.100391
2. [2]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
3. [3]
  Shunyu Wang , Yanan Zhu , Yang Zhao , Wanli Nie , Hong Meng . Steric effects and electronic manipulation of multiple donors on S₀/S₁ transition of D_n-A emitters. Chinese Chemical Letters, 2025, 36(4): 110555-. doi: 10.1016/j.cclet.2024.110555
4. [4]
  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
5. [5]
  Changlin Su , Wensheng Cai , Xueguang Shao . Water as a probe for the temperature-induced self-assembly transition of an amphiphilic copolymer. Chinese Chemical Letters, 2025, 36(4): 110095-. doi: 10.1016/j.cclet.2024.110095
6. [6]
  Jinpeng Du , Junlin Chen , Yulong Shan , Tongliang Zhang , Yu Sun , Zhongqi Liu , Xiaoyan Shi , Wenpo Shan , Yunbo Yu , Hong He . Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts. Chinese Chemical Letters, 2025, 36(3): 110019-. doi: 10.1016/j.cclet.2024.110019
7. [7]
  Chang Liu , Zirui Song , Xinglan Deng , Shihong Xu , Renji Zheng , Wentao Deng , Hongshuai Hou , Guoqiang Zou , Xiaobo Ji . Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors. Chinese Chemical Letters, 2024, 35(6): 109081-. doi: 10.1016/j.cclet.2023.109081
8. [8]
  Mengjia Luo , Yi Qiu , Zhengyang Zhou . Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4. Chinese Journal of Structural Chemistry, 2025, 44(1): 100446-100446. doi: 10.1016/j.cjsc.2024.100446
9. [9]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
10. [10]
  Lu Dai , Yuxin Ren , Shuang Li , Meidi Wang , Chentao Hu , Ya-Pan Wu , Guangtong Hai , Dong-Sheng Li . Room-temperature synthesis of Co(OH)₂/Mo₂TiC₂T_x hetero-nanosheets with interfacial coupling for enhanced oxygen evolution reaction. Chinese Chemical Letters, 2025, 36(4): 109774-. doi: 10.1016/j.cclet.2024.109774
11. [11]
  Yuxin Xiao , Xiaowei Wang , Yutong Yin , Fangchao Yin , Jinchao Li , Zhiyuan Hou , Mashooq Khan , Rusong Zhao , Wenli Wu , Qiongzheng Hu . Distance-based lateral flow biosensor for the quantitative detection of bacterial endotoxin. Chinese Chemical Letters, 2024, 35(12): 109718-. doi: 10.1016/j.cclet.2024.109718
12. [12]
  Bingyang Lu , Dehui Wang , Junchang Guo , Yang Shen , Qian Feng , Jinlong Yang , Xiao Han , Huali Yu , Luohuizi Li , Jiaxin Liu , Jing Luo , Huan Liu , Zhongwei Zhang , Xu Deng . High-efficiency exudates drainage of anti-adhesion dressings for chronic wound. Chinese Chemical Letters, 2025, 36(4): 110601-. doi: 10.1016/j.cclet.2024.110601
13. [13]
  Yu Zhang , Weifeng Lin . Electrotunable interfacial friction: A brief review. Chinese Chemical Letters, 2025, 36(4): 110566-. doi: 10.1016/j.cclet.2024.110566
14. [14]
  Yiyang Shen , Zhen Zhang , Ruyi Liang , Tongbo Wu . Unraveling the interplay of DNAzyme and interfacial factors for enhanced biosensing. Chinese Chemical Letters, 2024, 35(12): 109638-. doi: 10.1016/j.cclet.2024.109638
15. [15]
  Shengdong Sun , Cheng Wang , Shikuo Li . Interfacial channel design on the charge migration for photoelectrochemical applications. Chinese Journal of Structural Chemistry, 2024, 43(12): 100398-100398. doi: 10.1016/j.cjsc.2024.100398
16. [16]
  Kongchuan Wu , Dandan Lu , Jianbin Lin , Ting-Bin Wen , Wei Hao , Kai Tan , Hui-Jun Zhang . Elucidating ligand effects in rhodium(Ⅲ)-catalyzed arene–alkene coupling reactions. Chinese Chemical Letters, 2024, 35(5): 108906-. doi: 10.1016/j.cclet.2023.108906
17. [17]
  Yue WANG , Zhizhi GU , Jingyi DONG , Jie ZHU , Cunguang LIU , Guohan LI , Meichen LU , Jian HAN , Shengnan CAO , Wei WANG . Effects of kelp-derived carbon dots on embryonic development of zebrafish. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1209-1217. doi: 10.11862/CJIC.20230423
18. [18]
  Qiang Fu , Shouhong Sun , Kangzhi Lu , Ning Li , Zhanhua Dong . Boron-doped carbon dots: Doping strategies, performance effects, and applications. Chinese Chemical Letters, 2024, 35(7): 109136-. doi: 10.1016/j.cclet.2023.109136
19. [19]
  Luyao Lu , Chen Zhu , Fei Li , Pu Wang , Xi Kang , Yong Pei , Manzhou Zhu . Ligand effects on geometric structures and catalytic activities of atomically precise copper nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(10): 100411-100411. doi: 10.1016/j.cjsc.2024.100411
20. [20]
  . . University Chemistry, 2024, 39(6): 0-0.

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(582)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return