Citation: Wei Min ZHU, Zhi Fang LI, Yong Min ZHANG. Synthesis of Enamines via the Cross-coupling of Thioamides and Diarylketones Promoted by the Sm/SmI₂ Mixed Reagent[J]. Chinese Chemical Letters, ;2006, 17(1): 1-4. shu

Synthesis of Enamines via the Cross-coupling of Thioamides and Diarylketones Promoted by the Sm/SmI₂ Mixed Reagent

1.
Department of Chemistry, Zhejiang University, Xixi Campus, Hangzhou 310028;
2.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received Date: 11 April 2005

Fund Project: We are grateful to the National Natural Science Foundation of China (Project No. 20072033), and Specialized Research Fund for the Doctoral Program of Higher Education of China.

Enamines, promoted by the samarium/samarium diiodide mixed reagent, were synthesized via the cross-coupling of thioamides and diarylketones in good yields.
- Samarium,
- enamines,
- cross-coupling,
- thioamides,
- diarylketones
1. [1]
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