Citation: Li Ming DING, Zhong SHI, Hua Fang ZHOU, Shao Jun DONG. Physical Diffusion and Electron-transfer Dynamics of Electroactive Solutes in Polymer Electrolytes Ⅲ. Effect of the Polymer Solvents[J]. Chinese Chemical Letters, ;1997, 8(10): 901-904. shu

Physical Diffusion and Electron-transfer Dynamics of Electroactive Solutes in Polymer Electrolytes Ⅲ. Effect of the Polymer Solvents

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 8 May 1997

The diffusion coefficients(D_app) and the heterogeneous electron transfer rate constants(k_s) for ferrocene in several polymer solvents were determined by using steady-state voltammetry.The temperature dependence of the two parameters indicates Arrhenius behavior.The polymer solvent effects on diffusion and electron transfer dynamics of ferrocene were discussed.
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