Citation: Yan XU, Hai Xian WANG, Yong FU, Mao Ping SONG, Yang Jie WU. Synthesis and Crystal Structure of a Novel Hetero-six-nuclear Copper-iron Cluster Containing Ferroceylphenyl Groups[J]. Chinese Chemical Letters, ;2005, 16(7): 883-885. shu

Synthesis and Crystal Structure of a Novel Hetero-six-nuclear Copper-iron Cluster Containing Ferroceylphenyl Groups

Department of Chemistry, Henan Key Laboratory of Applied Chemistry, Henan Key Laboratory of Chemical Biology and organic chemistry, Zhengzhou University, Zhengzhou 450052

Received Date: 19 July 2004

Fund Project: We are grateful to the National Natural Science Foundation of China (project 20072034) and the Natural Science Foundation of Henan province and the Foundation for Young Teacher in Zhenzhou University for the financial support.

A new hetero-six-nuclear cluster was synthesized and determined by X-ray diffraction technique. The four-carboxylate groups are bound to the Cu(Ⅱ) atoms to form Cu(OR)₄Cu paddle-wheel-type cage between two DMF as the basis for the cluster. The distance of two copper(Ⅱ) atoms is 2.642 Å, and they are bridged by the carboxylate groups. A huge system plane was auto-assembled by four host molecules and two Cu (Ⅱ) ions, which was observed in the crystal structure.
- Ferrocene,
- hetero-six-nuclear cluster,
- copper,
- crystal structure
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