Citation: Wen Chun ZHANG, Zhong Heng YU. A Simple and Novel Ipso-Bromination of 1-Bromomethyl-4-t-butyl-2,6-dimethylbenzene[J]. Chinese Chemical Letters, ;1997, 8(4): 271-274. shu

A Simple and Novel Ipso-Bromination of 1-Bromomethyl-4-t-butyl-2,6-dimethylbenzene

Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080

Received Date: 5 December 1996

Fund Project: This work was supported by the National Natural Science Foundation of China.

A novel ipso electrophlic substitution of 1-bromomethyl-4-t-butyl-2,6-dimethylbenzene 1 with nitric acid in alcohol,which gives ipso-bromination product of 1-bromo-4-t-butyl-2,6-dimethylbenzene 2,is described,and a possible mechanism for this reaction is investigated.
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