Citation:
QIU Kunyuan, FU Jie GUO, Xinqiu, FENG Xinde. STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J]. Chinese Journal of Polymer Science,
;1990, 8(2): 188-195.
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The polymerization of methyl methacrylate (MMA) initiated by organic peroxide and polymerizable aromatic tertiary amine such as N, N-di (2-α-methylacryloyloxy propyl)-p-toluidine (MP)2PT binary system has been studied. It was found that the (MP)2PT promotes MMA polymerization, and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.
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