Citation: Chu Chi TANG, Gui Ping WU. A NEW CONVENIENT SYNTHESIS OF S-ALKYL N,N-DIALKYL THIOPHOSPHORAMIDIC ACID DERIVATIVES[J]. Chinese Chemical Letters, ;1992, 3(8): 593-594. shu

A NEW CONVENIENT SYNTHESIS OF S-ALKYL N,N-DIALKYL THIOPHOSPHORAMIDIC ACID DERIVATIVES

Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 27 January 1992

The chlorination of O,O-dialkyl N,N-dialkyl thiophosphoramidates with phosphorus oxychloride proceeds with isomerization to give S-alkyl N,N-dialkyl thiophosphoramidochloridates,which react further with various nucleophiles in the presence of base to give the title compounds.
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