Citation: . INTERACTION OF POLY(SODIUM SULFODECYL METHACRYLATE)WITH CETYLTRIMETHYL AMMONIUM BROMIDE IN AQUEOUS SOLUTION*[J]. Chinese Journal of Polymer Science, ;2003, 21(3): 353-357. shu

INTERACTION OF POLY(SODIUM SULFODECYL METHACRYLATE)WITH CETYLTRIMETHYL AMMONIUM BROMIDE IN AQUEOUS SOLUTION*

Received Date: 17 May 2002
Revised Date: 9 July 2002

The interaction of poly(sodium sulfodecyl methacrylate) (PSSM) with cetyltrimethyl ammonium bromide (CTAB)was studied. It was found that the precipitate formed from PSSM and CTAB will be dissolved by excessive CTAB, resultingin the appearance of two maxima of the solution viscosity at the molar ratio (CTAB/-SO3-) of≈ 0.68 and≈1.30,respectively. The first one is related closely to the aggregation of polymer chains via CTAB molecules and the second oneshould be ascribed to the formation of the mixed micelles comprising surfactant and the polymer's hydrophobic chains.The effect of NaCl on the viscosity,the transmittance of the aqueous solution and the solubility of oil-soluble dye (dimethyl yellow) in the mixed system were also investigated.
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