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Citation: Gao Haichun, Sun Changmin, Huo Yan, Zhang Ruifeng, Li Xinglin. XPS Study of Lithium Ion Conducting Oxysulfids Glasses[J]. Chinese Journal of Applied Chemistry, ;1995, 12(4): 102-104. shu

XPS Study of Lithium Ion Conducting Oxysulfids Glasses

1.
Institute of Salt Lakes, Chinese Academy of Sciences, Xining;
2.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 18 September 1994
Revised Date: 5 April 1995

The structtiral unit of network and chemical state of constituent elements for the oxysulfide glasses in the system Li₂S-B₂O₃-LiBr were studied by using X-ray photoelectron spectroscopy. The results indicate that sulfur in the form of S^2- participates in network for-mation of glasses as coordinated ion and the glasses with R < 0.4 have no nonbridging sulfur ions. So,the binding energies(BE) of S_2p do not show appreciable change with the variation of modifier Li₂S content. However, when R≥0.4,BE of S_2p significantly decreases with the addition of Li₂S that is caused by the existence of the nonbridging sulfur ions. The binding energy of Li_1s in the glasses is found to increase gradually with the increase of LiBr dopant content. This implies that LiBr is only dissolved in glass matrix entering the network inter-stitially as dissociated ions,and the Li^- ions surrounded by Br^- ions mainly take part in con-duction.
- solid electrolyte,
- lithium ion conductor,
- oxysuifide glass,
- XPS
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