Citation: Zhen XU, Ji Liang SHI, Xin CHEN, Xi Kui JIANG. ³¹P NMR Study on Some Phosphorus-Containing Compounds[J]. Chinese Chemical Letters, ;2000, 11(12): 1057-1060. shu

³¹P NMR Study on Some Phosphorus-Containing Compounds

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032

Received Date: 26 May 2000

³¹P NMR has become a widely applied spectroscopic probe of the structure of phosphorus-containing compounds. Meanwhile, the application of ³¹P NMR has been rapidly expanded to biochemistry and medicinal chemistry of phosphorus-containing compounds because the growing importance of the phosphorus compounds is now widely realized. We report here the results of ³¹P NMR study on some phosphorus-containing compounds, namely, O-alkyl O-4-nitrophenyl methyl phosphonates with different alkyl chain-length (MePO-n), 4-nitrophenyl alkylphenylphosphinates with different alkyl chain-length (PhP-n), diethyl phosphono-acetonitrile anion and diethyl phosphite anion. Our results indicate that ³¹P NMR can not only be applied to not only the study of the hydrolytic reactions of MePO-8 and PhP-8 but also be applied to the study of the presence of the anions of diethylphosphonoacetonitrile and diethyl phosphite in nucleophilic reactions.
- ³¹P NMR,
- phosphorus-containing compounds,
- nucleophilic reaction
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