Citation: Wan Yong MA, Da Cheng FENG, Zheng Ting CAI, Cong Hao DENG. The Quantum Scattering Study for Ion-pair Formation Reaction Na+I₂→Na⁺+I₂^- with the LCAC-SW method[J]. Chinese Chemical Letters, ;1999, 10(4): 325-326. shu

The Quantum Scattering Study for Ion-pair Formation Reaction Na+I₂→Na⁺+I₂^- with the LCAC-SW method

Institute of Theoretical Chemistry, Shandong University, Jinan 250100

Received Date: 18 September 1998

Fund Project: Pro ject supported by the National Natural Science Foundation of China (No. 29673026).

The selected-state probabilities of collinear ion-pair formation process Na+I₂→Na⁺+I₂^- on Aten-Laming-Los two-state potential energy surface have been calculated by using LCAC-SW method. The results show that reaction probabilities are oscillatory with collision energy; the threshold energy of this ionization reaction is 2.8 ev, which is in modest agreement with experimental result.
- Ion-pair formation,
- reaction probability,
- quantum scattering,
- LCAC-SW method
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