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Citation: Yang Chuncai, Jing Xiabin, Wang Huabin, Chen Tianlu, Han Xiaozu, Wang Fosong. Synthesis and Poling of A Crosslinked Second Order Nonlinear Optical Polymer with Liquid Crystalline Side Groups[J]. Chinese Journal of Applied Chemistry, ;1995, 12(4): 7-12. shu

Synthesis and Poling of A Crosslinked Second Order Nonlinear Optical Polymer with Liquid Crystalline Side Groups

Polymer Pliysics Laboratory, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 19 August 1994
Revised Date: 19 October 1994

The synthesis of glycerin monoether of 4-[(p-nitrophenyl) azoxy] phenol which can form liquid crystalline phases is reported. The crosslinking reaction of glycerin mo-noether of 4-[(p-nitrophenyl) azoxy] phenol by biuret of hexamethylene diisocyanate has been studied by DSC and FTIR spectra. The orientation and stability of a poled and crosslinked polymer have been investigated by UV-Vis spectra. The orientation relaxation was not observed in 100 hours for the poled and crosslinked polymer after poling and crosslinking for 1h at 150℃.
- azoxybenzene,
- crosslinked polymer,
- liquid crystal,
- corona poling,
- nonlinear optical polymer
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