Citation: Wei Hong SONG, Xuan Zhen JIANG. A Novel Synthesis of Diethyl Malonate[J]. Chinese Chemical Letters, ;2000, 11(12): 1035-1036. shu

A Novel Synthesis of Diethyl Malonate

Department of Chemistry, University of Zhejiang, Hangzhou 310027

Received Date: 22 May 2000

A green synthesis route of diethyl malonate by palladium catalyzed carbonylation of ethyl chloroacetate in the presence of phase transfer agent is carried out under mild conditions in good yield. The effects of reaction temperature and different bases on the yield of diethyl malonate are also discussed.
- Diethyl malonate,
- phase transfer agent,
- carbonylation
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