Citation: Cong ZHANG, Xiao Chuan GUO, Xiu Min SHEN, Yong Fen XU. ACID CATALYZED REARRANGEMENTS OF TRIQUINANES[J]. Chinese Chemical Letters, ;1995, 6(3): 177-180. shu

ACID CATALYZED REARRANGEMENTS OF TRIQUINANES

Institute of Organic Chemistry, National Laboratory of Applied Organic Chemistry at Lanzhou University, Lanzhou, 730000

Received Date: 18 October 1994

Fund Project: This project was supported financially by the NNSFC and the State Education Commission of China.

Acid catalyzed rearrangements of 1 and 3 were examined.The olefinic double bond was the most reactive group in protonation reaction.In the absence of olefinic double bond,tert-hydroxy group reacted faster than cyclopropane ring.
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