Citation: Sheng Lin LIU, Long Ya XU, Su Juan XIE, Qing Xia WANG. Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide[J]. Chinese Chemical Letters, ;2001, 12(1): 43-46. shu

Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide

Group 804 Dalian Institute of Chemical Physics CAS P O Box 110 Dalian 116023

Received Date: 15 June 2000

The partial oxidation of butane (POB) to syngas over nickel supported catalysts was first investigated with a flow-reactor, TG and UVRRS. The NiO/γ-Al₂O₃ is the most suitable for the POB among NiO/γ-Al₂O₃, NiO/MgO and NiO/SiO2. And the reaction performance of the NiO/γ-Al₂O₃ shows little difference from those of the nickel supported catalysts modified by alkali metal oxide and rare-earth metal oxide. However, modification with Li₂O and La₂O₃ can suppress carbon-deposition of the NiO/γ-Al₂O₃, which contains graphite-like species during the POB reaction.
- Partial oxidation of butane,
- syngas,
- carbon-deposition,
- nickel supported catalysts.
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