Citation: Bi Tao ZHAO, Hua Jie ZHU, Xing HONG, Jun ZHOU, Xiao Jiang HAO. Chiral Ligands from Abrine.4. Hete rocycle-Containing 1,2,3,4-Tetrahydro-β-Carboline Methyl Ester Used for C atalysis of Enantioselective Addition of Diethylzinc to Benzaldehyde[J]. Chinese Chemical Letters, ;1998, 9(6): 527-528. shu

Chiral Ligands from Abrine.4. Hete rocycle-Containing 1,2,3,4-Tetrahydro-β-Carboline Methyl Ester Used for C atalysis of Enantioselective Addition of Diethylzinc to Benzaldehyde

KunAnng Institute of Botany, Chinese Academy of Sciences, Heilongtan, Kunming 650204

Received Date: 25 February 1998

Fund Project: The work was supported by the Young Investigator Grant from the Science and Technology Committee of the Yunnan Province of China, to Dr. Hua-Jie Zhu, and by the National Foundation for Outstanding Young Scientists to Prof. Xiao-Jiang Hao.

Four 1,2,3,4-tetrahydro-β-carboline amino acid esters with a heterocycle at the C-l position were used as chiral ligands in the enantioselective addition reactions. The different positions of the heteroatoms gave different effects, and medium but opposite enantioselectivity was recorded.
- Enantioselective addition,
- diethylzinc,
- 1,2,3,4-tetrahydro-β-carboline ester
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