Citation: ZHANG XingHua, Robert West. ORGANOSILANE POLYMERS: SYNTHESIS AND CROSSLINKING OF FORMABLE POLYMERS CONTAINING PHENYLSILYLENE UNITS[J]. Chinese Journal of Polymer Science, ;1987, 5(3): 240-253. shu

ORGANOSILANE POLYMERS: SYNTHESIS AND CROSSLINKING OF FORMABLE POLYMERS CONTAINING PHENYLSILYLENE UNITS

Received Date: 13 November 1986

Polysilane polymers which contain silicon hydride units in the chain were synthesized by sodium coupling of PhHSiCl2 with R1R2SiCl2 in toluene (R1 and R2 alkyl, aryl or aralkyl), followed by termination with a monochlorosilane and neutralization with sodium bicarbonate solution. These polymers are soluble in common solvents and can be formed into a variety of shapes by molding, casting, coating or potting. This class of polymers can be crosslinked by oxidation and irradiation, or by reaction with a multifunctional vinylsilane in th presence of platinum complexes.
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