Citation: Wen Hua SUN, Shi Yan YANG, Yuan Ci YIN, Kai Bei YU, Zhong Yuan ZHOU. SYNTHESIS,CHARACTERIZATION AND CRYSTAL STRUCTURES OF (η⁵-CH₃C₅H₄)M(CO)₂NO AND(η⁵-CH₃C₅H₄)M(μ₃-NH)(μ₂-NO)(μ₂-CO)Fe₂(CO)₆(M=Mo or W)[J]. Chinese Chemical Letters, ;1991, 2(3): 263-266. shu

SYNTHESIS,CHARACTERIZATION AND CRYSTAL STRUCTURES OF (η⁵-CH₃C₅H₄)M(CO)₂NO AND(η⁵-CH₃C₅H₄)M(μ₃-NH)(μ₂-NO)(μ₂-CO)Fe₂(CO)₆(M=Mo or W)

a Lanzhou Institute of Chemical Physics Chinese Academy of Sciences, Lanzhou 730000;
b Chengdu Center of Analysis and Test Chinese Academy of Sciences, Chengdu 610015

Received Date: 28 November 1990

Synthesis of complexes (η⁵-CH₃C₅H₄) M(CO)₂NO (M=Mo, I;M=W, Ⅱ) and clusters (η⁵-CH₃C₅H₄) M (μ₃-NH) (μ₂-NO) (μ₂-CO) Fe₂(CO)₆ (M=Mo, Ⅲ:M=W, IV), based on the reaction of (η⁵-C₅H₄) M(CO)₃Cl with Na[Fe(CO)₃NO] at room tem-perature, have been demonstrated, The crystal structures of Ⅱ and IV are also presented.
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